Faculty of Frontiers of Innovative Research in Science and Technology

Papers -

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Co-generation of palladium nanoparticles and phosphate supported on metal-organic frameworks as hydrogenation catalysts Reviewed

Yohei Takashima, Seiko Tetsusashi, Mai Takano, Shintaro Tanaka, Yui Murakami, Takaaki Tsuruoka, Kensuke Akamatsu

Dalton Trans. 52 11158 - 11162 2023.7

Authorship：Lead author,　Corresponding author

Other Link： https://pubs.rsc.org/en/content/articlelanding/2023/dt/d2dt04109j

The iron chelator deferriferrichrysin induces paraptosis via extracellular signal-related kinase activation in cancer cells Invited Reviewed

Natsuki Kinoshita, Masaya Gessho, Takeru Torii, Yukako Ashida, Minori Akamatsu, Alvin Kunyao Guo, Sunmin Lee, Tatsuya Katsuno 3, Wataru Nakajima Yemima Budirahardja, Daisuke Miyoshi, Takehiko Todokoro, Hiroki Ishida, Takahito Nishikata, Keiko Kawauchi

Genes Cells 28 ( 9 ) 653 - 662 2023.6

DOI： 10.1111/gtc.13053

Quantification of the concentration in a droplet formed by liquid–liquid phase separation of G-quadruplex-forming RNA Reviewed

Kohei Yokosawa, Mitsuki Tsuruta, Shinji Kajimoto, Naoki Sugimoto, Daisuke Miyoshi, Takakazu Nakabayashi

Chem. Phys. Lett. 826 140634 - 140634 2023.6

Publisher：Elsevier BV

DOI： 10.1016/j.cplett.2023.140634

Simple and fast screening for structure-selective G-quadruplex ligands. Reviewed International journal

Yoshiki Hashimoto, Yoshiki Imagawa, Kaho Nagano, Ryuichi Maeda, Naho Nagahama, Takeru Torii, Natsuki Kinoshita, Nagisa Takamiya, Keiko Kawauchi, Hisae Tatesishi-Karimata, Naoki Sugimoto, Daisuke Miyoshi

Chemical communications (Cambridge, England) 59 ( 33 ) 4891 - 4894 2023.4

Joint Work

Structural selectivity of G-quadruplex ligands is essential for cellular applications since there is an excess of nucleic acids forming duplex structures compared to G-quadruplex structures in living cells. In this study, we developed new structure-selective G-quadruplex ligands utilizing a simple and fast screening system. The affinity, selectivity, enzymatic inhibitory activity and cytotoxicity of the structure-selective G-quadruplex ligands were demonstrated along with a structural selectivity-cytotoxicity relationship of G-quadruplex ligands.

DOI： 10.1039/d3cc00556a

PubMed

Not all 2',4'-bridged modifications stabilize DNA/RNA duplexes Reviewed

Tomoka Akita, Elisa Tomita-Sudo, Shin Itoh, Nae Sakimoto, Takeshi Masuda, Akifumi Nakamura, Yoshiyuki Onishi, Makoto Koizumi, Junji Kawakami

Nucleosides, Nucleotides & Nucleic Acids 43 ( 1 ) 57 - 64 2023.3

Authorship：Last author,　Corresponding author

Biomolecular Liquid–Liquid Phase Separation for Biotechnology Invited Reviewed

Sumit Shil, Mitsuki Tsuruta, Keiko Kawauchi and Daisuke Miyoshi

BioTech 12 ( 2 ) 26 2023.3

Authorship：Corresponding author

DOI： 10.3390/biotech12020026

The role of G-quadruplex in expression of retrotransposon LINE-1 Invited

23 48 - 48 2023.3

Construction of a Method to Design Fibril-Forming Peptides Applied to Biomaterials from 20 Beta-Sheet Peptides by Statistical Analysis Reviewed

Kazuya Iwata, Taisei Terao, Akira Takekawa, Tomohiro Umetani, Kenji Usui

Peptide Science 2022 141 - 142 2023.3

Authorship：Last author,　Corresponding author

High-performance bulk Bi0.4Sb1.6Te3.0 thermoelectrics prepared from nanocrystal precursor synthesized via chemical precipitation Reviewed

Ryosuke Fujiwara, Yohei Takashima, Takaaki Tsuruoka, Muneyuki Naito, Junya Murai, Kensuke Akamatsu

Journal of Solid State Chemistry 319 123777 - 123777 2023.3

Publisher：Elsevier BV

DOI： 10.1016/j.jssc.2022.123777

Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst Reviewed

Yohei Takashima, Seiko Tetsusashi, Shintaro Tanaka, Takaaki Tsuruoka, Kensuke Akamatsu

RSC Adv. 13 7464 - 7467 2023.3

Authorship：Lead author

Other Link： https://pubs.rsc.org/en/content/articlelanding/2023/ra/d2ra08190c

Simple and fast screening for structure-selective G-quadruplex ligands Reviewed International journal

Chem. Commun. 59 ( 33 ) 4891 - 4894 2023.2

Authorship：Corresponding author

DOI： 10.1039/D3CC00556A

PubMed

Morphological Evidence for Novel Roles of Microtubules in Macrophage Phagocytosis Reviewed

Seta Y, Kawakatsu K, Degawa S, Goto T, Nishikata T

International Journal of Molecular Science 24 1373 2023.1

Joint Work

Authorship：Last author,　Corresponding author

DOI： doi.org/10.3390/ijms24021373

High-performance bulk Bi0.4Sb1.6Te3.0 thermoelectrics prepared from nanocrystal precursor synthesized via chemical precipitation

R. Fujiwara, Y.Takashima, T. Tsuruoka, M. Naito, J. Murai, K. Akamatsu

Journal of Solid State Chemistry 319 123777 2023

“Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst

Y. Takashima, S. Tetsusashi, S. Tanaka, T. Tsuruoka, K. Akamatsu

RSC Adv 13 7464 - 7467 2023

“Co-generation of palladium nanoparticles and phosphate supported on metal-organic frameworks as hydrogenation catalysts

Y. Takashima, S. Tetsusashi, M. Takano, S. Tanaka, Y. Murakami, T. Tsuruoka, K. Akamatsu

Dalton Trans 52 11158 - 11162 2023

Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst Reviewed

Yohei Takashima, Seiko Tetsusashi, Shintaro Tanaka, Takaaki Tsuruoka, Kensuke Akamatsu

RSC Advances 13 ( 11 ) 7464 - 7467 2023

Publisher：Royal Society of Chemistry (RSC)

Polypyrrole-coated palladium nanoparticles could be directly generated inside a metal–organic frameworks. The resulting MOF composites exhibited higher semihydrogenation capability than the analog composite without polypyrrole coating.

DOI： 10.1039/d2ra08190c

Co-generation of palladium nanoparticles and phosphate supported on metal–organic frameworks as hydrogenation catalysts Reviewed

Yohei Takashima, Seiko Tetsusashi, Mai Takano, Shintaro Tanaka, Yui Murakami, Takaaki Tsuruoka, Kensuke Akamatsu

Dalton Transactions 52 ( 32 ) 11158 - 11162 2023

Publisher：Royal Society of Chemistry (RSC)

In this study, we demonstrated the direct synthesis of sodium dihydrogen phosphate (PA) containing palladium nanoparticles (PdNPs) supported on a metal–organic framework (MOF) for hydrogenation catalysis.

DOI： 10.1039/d2dt04109j

Evaluation of thermal stability of DNA oligonucleotide structures embedded in hydrogels Invited Reviewed International journal

D. Yamaguchi, M. Yoshida, S. Nakano

DNA 2 ( 4 ) 302 - 313 2022.12

Joint Work

Authorship：Last author,　Corresponding author Publisher：MDPI

Understanding the self-assembly and hybridization properties of DNA oligonucleotides in confined spaces can help to improve their applications in biotechnology and nanotechnology. This study investigates the effects of spatial confinement in the pores of hydrogels on the thermal stability of DNA oligonucleotide structures. The preparation of oligonucleotides embedded in agarose gels was simple, whereas the preparation of oligonucleotides embedded in polyacrylamide gels was required to remove unpolymerized monomers. In the latter case, a method for rehydrating a washed dry gel with a buffer solution containing oligonucleotides was developed. Fluorescence measurements of oligonucleotides bearing fluorescent probes revealed no significant influence of the internal environment of the gel pores on the stability of DNA duplex, hairpin, and G-quadruplex structures. Moreover, the effects of poly(ethylene glycol) on the stability of DNA structures in the gels were similar to those in solutions. It is likely that the oligonucleotides are not strongly constrained in the gels and may be preferentially located in a water-rich environment in the gel matrix. The gel preparation was also applied to the assessment of the stability of DNA structures under the conditions of a reduced number of water molecules. The studies using hydrogels provide insights into the ability of self-assembly and hybridization of oligonucleotides in confined environments and under low-water-content conditions.

DOI： 10.3390/dna2040021

Controlling liquid-liquid phase separation of G-quadruplex-forming RNAs in a sequence-specific manner. Reviewed International journal

Mitsuki Tsuruta, Takeru Torii, Kazuki Kohata, Keiko Kawauchi, Hisae Tateishi-Karimata, Naoki Sugimoto, Daisuke Miyoshi

Chemical communications (Cambridge, England) 58 ( 93 ) 12931 - 12934 2022.11

Joint Work

We constructed a minimum liquid-liquid phase separation model system to form liquid droplets using only G-quadruplex-forming oligonucleotides and R- and G-rich oligopeptides. We found that the G-quadruplex structure is an essential component for RNA to form droplets with the peptide. Based on this model system and our findings, droplet redissolution via structure transition from a G-quadruplex to a duplex was achieved in a sequence-specific manner.

DOI： 10.1039/d2cc04366a

PubMed

Covalent Stem Cell-Combining Injectable Materials with Enhanced Stemness and Controlled Differentiation In Vivo Reviewed

Natsumi Ueda, Shiho Sawada, Fumiya Yuasa, Karen Kato, Koji Nagahama

ACS Applied Materials & Interfaces 14 ( 47 ) 52618 - 52633 2022.11

Authorship：Last author,　Corresponding author

DOI： https://doi.org/10.1021/acsami.2c12918

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