Review Papers (Misc) -
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金ナノ粒子とバイオセンシング
赤松謙祐、杉本直己
化学 57 28 - 31 2002
Publishing type：Article, review, commentary, editorial, etc. (international conference proceedings) Publisher：化学同人
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LSIインターコネクションへの銅めっき法の適用
縄舟秀美、赤松謙祐
Electrochemistry 70 880 - 884 2002
Publishing type：Article, review, commentary, editorial, etc. (international conference proceedings) Publisher：a
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Effect of composition and structure of gold/copper bimetallic nanoparticles on dispersion in polymer thin films
J. Mater. Chem 12 ( 12 ) 3610 - 3614 2002
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金ナノ粒子とバイオセンシング
赤松 謙祐
化学 57 28 - 31 2002
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フリップチップ実装を目的としたスルホコハク酸浴からのスズ―インジウム共晶合金の電析
縄舟 秀美, 中谷 敏雄, 赤松 謙祐, 水本 省三, 小幡 恵吾, 内田 衛
エレクトロニクス実装学会誌 5 ( 4 ) 349 - 352 2002
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Novel copper electroless plating process on ceramic substrate using copper oxide
Electrochem.Solid State Lett. 5 ( 9 ) C87 - C89 2002
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Microstructure and electron transport properties of AuxCo1-x nano-alloys embedded in polyacrylonitrile thin films
J.Master.Chem. 12 ( 8 ) 2408 - 2411 2002
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LSIインターコネクションへの銅めっき法の適用
赤松 謙祐
電気化学および工業物理化学 70 880 - 884 2002
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Highly reactive intermediate-functionalized gold clusters: Synthesis and immobilization on silica supports through amide-forming coupling
J.Master.Chem. 12 ( 10 ) 2862 - 2865 2002
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Growth of metal oxide thin films from aqueous solution by liquid phase depositiono, LPD, method
Solid State Ionics 151 ( 1/4 ) 1 - 9 2002
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Fabrication and characterization of PAN-derived carbon thin films containing Au nanoparticles
Thin Solid Films 408 ( 1/2 ) 59 - 63 2002
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鉛フリーはんだ接合を目的としたスルホコハク酸浴からのSn-0.7Cu-0.3Ag３元合金の電析
縄舟秀美、芝一博、赤松謙祐、水本省三、内田衛、小幡恵吾
エレクトロニクス実装学会誌 5 ( 2 ) 146 - 151 2002
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Preparation of novel heteroisoindoles from nitro pyridines and nitro pyridones
Heterocycles 58, 301-310 2002
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Construction of a Protein-Detection System using Designed Peptides with Fluorescent Labels
K. Usui, M. Takahashi, A. Ueno, K. Nokihara, H. Mihara
Peptide Science 2001 405 - 406 2002
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核酸における超ワトソン・クリックモデルの試み カチオンと非ワトソン・クリック型塩基の役割を考える
杉本直己・中野修一
化学と生物 39 ( 11 ) 714 - 722 2001.11
Publishing type：Article, review, commentary, editorial, etc. (international conference proceedings) Publisher：日本農芸化学会
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Chemical modification of curdlan to induce an interaction with poly(C)(1)
K Koumoto, T Kimura, H Kobayashi, K Sakurai, S Shinkai
CHEMISTRY LETTERS ( 9 ) 908 - 909 2001.9
Publisher：CHEMICAL SOC JAPAN
The molecular weight of the commercially available curdlan is over 10(6), which makes it difficult to bind to polynucleotides. This paper presents a chain-scission reaction of curdlan and the molecular weight dependence of the binding ability. We found that curdlan can bind to poly(C) when the molecular weight is less than about 10(5). However, the complex stability is still less than that of the single chain of schizophyllan.
DOI： 10.1246/cl.2001.908
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Organization of nucleosides supported by boronic-acid-appended poly(L-lysine): Creation of a novel RNA mimic
H Kobayashi, M Amaike, K Koumoto, S Shinkai
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 74 ( 7 ) 1311 - 1317 2001.7
Publisher：CHEMICAL SOC JAPAN
Boronic-acid-appended poly(L-lysine) (1) can form anionic boronate esters with diol derivatives in aqueous solution. One can thus expect that when nucleosides are mixed with 1, the resultant complexes will satisfy the basic structural characteristics of RNA, viz., one-dimensionally organized nucleic bases and anionic charges. To obtain insights into this novel RNA mimic, the solution properties of adenosine (Ad) were estimated in the absence and the presence of 1. The large absorption and CD spectral changes were observed at pH 6-10 where the poly(L-lysine) main chain tends to adopt an a-helix-rich conformation. On the basis of the fact that the magnitude of the spectral changes is much larger than the fraction of complexed Ad molecules, the polymer-supported organization mode was proposed: that is, Ad molecules complexed by covalent bonds with I act as clusters to induce further organization of uncomplexed Ad molecules by noncovalent interactions. The proposal was further confirmed by H-1 NMR spectroscopy and dynamic light scattering, On the other hand, none of these spectral changes were observed for 2 ' -deoxyadenosine. The I-Ad complex thus formed can interact with complementary poly(U) but not with noncomplementary poly(C), indicating that it can act as a novel RNA mimic.
DOI： 10.1246/bcsj.74.1311
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Polysaccharide-polynucleotide complexes (IV): Antihydrolysis effect of the schizophyllan/poly(C) complex and the complex dissociation induced by amines
K Koumoto, T Kimura, K Sakurai, S Shinkai
BIOORGANIC CHEMISTRY 29 ( 3 ) 178 - 185 2001.6
Publisher：ACADEMIC PRESS INC
Polymer complexes formed by schizophyllan and poly(C) showed a unique antihydrolysis effect when poly(C) was subjected to hydrolysis under basic conditions. The complexation reduced the hydrolysis rate to 80% of the control (i.e., poly(C) itself). However, when we added oligoamines with the intention of catalyzing the hydrolysis, the oligoamines induced dissociation of the complex instead of acceleration of the hydrolysis. (C) 2001 Academic Press.
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TEM and SEM observations of super-structures constructed in organogel systems from a combination of boronic-acid-appended bola-amphiphiles with chiral diols
K Koumoto, T Yamashita, T Kimura, R Luboradzki, S Shinkai
NANOTECHNOLOGY 12 ( 1 ) 25 - 31 2001.3
Publisher：IOP PUBLISHING LTD
Two bola-amphiphilic alpha, omega -diboronic acids separated by a (CH(2))(11) or (CH(2))(12) group were synthesized. Complexation with chiral diols readily gave new amphiphiles end-capped with the chiral substituents. Some of these acted as good gelators of organic solvents. Transmission electron microscope and scanning electron microscope observations established that a variety of super-structures are created in the organogels, depending on the solvents and the structure of the chiral end-cap groups. In most cases, the fibrous aggregates, the network structure which is the driving-force for gelation, showed a helical higher-order structure reflecting the chirality of the end-cap groups. The results indicate that the combinatorial approach utilizing boronic acid functions and diol compounds is useful in creating a variety of new super-structures in the gel phase.
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A novel technique to specifically separate RNAs by Schizophyllan
Taro Kimira, Kazuya Koumoto, Masami Mizu, Ritsuko Kobayashi, Kazuo Sakurai, Seiji Shinkai
Nucleic Acids Res. Supplement 1 283 - 284 2001