Papers - TAKASHIMA Yohei
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Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst Reviewed
Yohei Takashima, Seiko Tetsusashi, Shintaro Tanaka, Takaaki Tsuruoka, Kensuke Akamatsu
RSC Adv., 13, 7464-7467 (2023). 13 7464 - 7467 2023.3
Authorship:Lead author
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High-performance bulk Bi0.4Sb1.6Te3.0 thermoelectrics prepared from nanocrystal precursor synthesized via chemical precipitation
Ryosuke Fujiwara, Yohei Takashima, Takaaki Tsuruoka, Muneyuki Naito, Junya Murai, Kensuke Akamatsu
Journal of Solid State Chemistry 319 123777 - 123777 2023.3
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High-performance bulk Bi0.4Sb1.6Te3.0 thermoelectrics prepared from nanocrystal precursor synthesized via chemical precipitation
R. Fujiwara, Y.Takashima, T. Tsuruoka, M. Naito, J. Murai, K. Akamatsu
Journal of Solid State Chemistry 319 123777 2023
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Cooperative catalysis in a metal–organic framework via post-synthetic immobilisation Reviewed
Yohei Takashima, Yuya Suwaki, Takaaki Tsuruoka and Kensuke Akamatsu
Dalton Transactions 51 ( 24 ) 9229 - 9232 2022.6
Authorship:Lead author, Corresponding author Publisher:Royal Society of Chemistry (RSC)
A Co-salen complex and a MOF were successfully hybridized by post-synthetic immobilization for a cooperative catalytic system.
DOI: 10.1039/d2dt01544g
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Chemical synthesis of single nanometer-sized Bi2−xSbxTe3.0 nanocrystals via direct precipitation process Invited Reviewed
Ryosuke Fujiwara, Yohei Takashima, Takaaki Tsuruoka, Muneyuki Naito, Junya Murai, Kensuke Akamatsu
Results in Chemistry 4 100485 - 100485 2022.1
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Rational and site-selective formation of coordination polymer consisiting of d10 coinage metal ions with thiolate ligands using metal ion-doped polymer substrate
T. Tsuruoka, Y. Miyashita, R. Yoshino, M. Fukuoka, S. Hirao, Y. Takashima, A. Demessence, K. Akamatsu
RSC Adv 12 3716 - 3720 2022
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Chemical synthesis of single nanometer-sized Bi2-xSbxTe3.0 nanocrystals via direct precipitation process
R. Fujiwara, Y.Takashima, T. Tsuruoka, M. Naito, J. Murai, K. Akamatsu
Results in Chemistry 4 100485 2022
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ポリイミド基板上への選択的金属有機構造体の形成技術
福岡美海、江口慧一、髙嶋洋平、赤松謙祐、鶴岡孝章
ポリイミドの高機能設計と応用技術 6 ( 6 ) 487 - 495 2022
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Supercapacitor electrode with high charge density based on boron-doped porous carbon derived from covalent organic frameworks Reviewed
Shigeyuki Umezawa, Takashi Douura, Koji Yoshikawa, Yohei Takashima, Mika Yoneda, Kazuma Gotoh, Vlad Stolojan, S. Ravi P. Silva, Yasuhiko Hayashi, Daisuke Tanaka
Carbon 184 418 - 425 2021.10
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Controlling Interfacial Ion-Transport Kinetics Using Polyelectrolyte Membranes for Additive- and Effluent-free, High-Performance Electrodeposition Reviewed International journal
Kensuke Akamatsu, Shu-ichi Nakano, Koshi Kimura, Yohei Takashima, Takaaki Tsuruoka, Hidemi Nawafune, Yuki Sato, Junya Murai, Hiroshi Yanagimoto
ACS Applied Materials & Interfaces 13 ( 11 ) 13896 - 13906 2021.3
Publisher:American Chemical Society (ACS)
The development of high-performance, environmentally friendly electrodeposition processes is critical for emerging coating technologies because current technologies use highly complex baths containing metal salts, supporting electrolytes, and various kinds of organic additives, which are problematic from both environmental and cost perspectives. Here, we show that a 200 μm-thin polyelectrolyte membrane sandwiched between electrodes effectively concentrates metal ions through interfacial penetration, which increases the conductance between the electrodes to 0.30 S and realizes solid-state electrodeposition that produces no mist, sludge, or even waste effluent. Both, experimental results and theoretical calculations, reveal that electrodeposition is controlled by ion penetration at the solution/polyelectrolyte interface, providing an intrinsically different ion-transport mechanism to that of conventional diffusion-controlled electrodeposition. The setup, which includes 0.50 mol L-1 copper sulfate and no additives, delivers a maximum current density of 300 mA cm-2, which is nearly fivefold higher than that of a current commercial plating bath containing organic additives.
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Exploration of structural transition phenomenon in flexible metal-organic framework formed on polymer substrate
S. Hirao, R. Hamagami, T. Ohhashi, K. Eguchi, N. Kubo, Y. Takashima, K. Akamatsu, T. Tsuruoka
CrystEngComm 23 8498 - 8505 2021
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Controlling Interfacial Ion-Transport Kinetics Using Polyelectrolyte Membranes for Additive- and Effluent-free, High-Performance Electrodeposition
ACS Appl. Mater. Interfaces 13 13896 - 13906 2021
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Precisely Controlled Reproducible Synthesis of Palladium Nanoparticles inside Metal-Organic Frameworks with H2 Gas as Reductant: Effects of Framework Crystallinity and H2 Gas Reviewed
Y. Takashima, Y. Sato, N.Kubo, T. Tsuruoka, K. Akamatsu
Chem. Lett 50 244 - 247 2021
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Shoya Hirao, Ruho Hamagami, Takashi Ohhashi, Keiichi Eguchi, Neo Kubo, Yohei Takashima, Kensuke Akamatsu, Takaaki Tsuruoka
CrystEngComm 23 ( 48 ) 8498 - 8505 2021
Publisher:Royal Society of Chemistry (RSC)
We investigate the structural transition of directly formed flexible MOF crystals on a polymer substrate.
DOI: 10.1039/d1ce01383a
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Coordination-Driven Self-Assembly on Polymer Surface for Efficient Synthesis of [Au(SPh)]n Coordination Polymer-Based Films Reviewed
T. Tsuruoka, T. Ohhashi, J. Watanabe, R. Yamda, S. Hirao, Y. Takashima, A. Demessence, S. Vaidya, O. Veselska, A. Fateeva, K. Akamatsu
Cryst. Growth Des 20 ( 3 ) 1961 - 1968 2020
Joint Work
We describe a simple bottom-up strategy to generate [Au(SPh)] (SPh: thiophenolate) coordination polymer (CP) based thin films by employing an interfacial self-assembly on a nylon substrate. This method utilizes Au ion-doped nylon film as a precursor of [Au(SPh)] CP and a support substrate to control the kinetics of the reduction of the Au ion from Au(III) to Au(I) and the complexation of Au(I) ions as well as SPh on the surface of the nylon film. The obtained CPs exhibit a fibril morphology with high crystallinity, which leads to a luminescent property. Further, we systematically study the formation mechanism of [Au(SPh)] CPs on the substrates. Amorphous CPs formed at an early stage of reaction are transformed to crystalline CPs based on the rearrangement of components during the reaction. The findings described herein offer novel and interesting openings for the synthesis of Au ion-based CPs that demonstrate desired functions for a wide range of applications. n n n
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Y. Takashima, Y. Sato, T. Tsuruoka, K. Akamatsu
Dalton Trans 49 ( 47 ) 17169 - 17172 2020
Joint Work
Authorship:Lead author, Corresponding author Publisher:Royal Society of Chemistry (RSC)
<p>In this work, by using a series of amine–boranes as vapour phase reductants, we succeeded in synthesizing Ag nanoparticles in a controlled manner inside MOFs.</p>
DOI: 10.1039/d0dt03259j
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Formation of Metal-Organic Frameworks on Metal Ion-Doped Polymer Substrate: In-Depth Time-Course Analysis using Scanning Electron Microscopy Reviewed
T. Tsuruoka, M. Hata, S. Hirao, T. Ohhashi, Y. Takashima, K. Akamatsu
Langmuir 35 10390 - 10396 2019.7
Joint Work
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Control of the nucleation and growth processes of metal-organic frameworks using a metal ion-doped polymer substrate for the construction of continuous films Reviewed
T. Ohhashi, T. Tsuruoka, Y. Takashima, K. Akamatsu
CrystEngComm 21 4851 - 4854 2019.7
Joint Work
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Integrated Synthesis of Gold Nanoparticles Coated with Polyoxometalate Clusters Reviewed
Sergio Martin, Yohei Takashima, Chang-Gen Lin, Yu-Fei Song, Haralampos N. Miras, Leroy Cronin
Inorganic Chemistry 58 ( 7 ) 4110 - 4116 2019.3
Joint Work
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固液界面での選択的MOF形成
鶴岡孝章、平尾翔也、髙嶋洋平、赤松謙祐
日本接着学会誌 55 301 - 307 2019
Joint Work